Πέμπτη 22 Νοεμβρίου 2018

Formation of a supramolecular charge-transfer complex. Ultrafast excited state dynamics and quantum-chemical calculations

GA?id=C8PP00328A

Photochem. Photobiol. Sci., 2019, Advance Article
DOI: 10.1039/C8PP00328A, Paper
Valery V. Volchkov, Mikhail N. Khimich, Mikhail V. Rusalov, Fedor E. Gostev, Ivan V. Shelaev, Viktor A. Nadtochenko, Artem I. Vedernikov, Sergey P. Gromov, Alexandra Ya. Freidzon, Michael V. Alfimov, Mikhail Ya. Melnikov
The relaxation scheme of the 1·3 singlet state excited by a 25 fs laser pulse was proposed. It includes very fast vibrational relaxation, and direct and back electron transfer resulting in complete fluorescence quenching.
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