Initial metal-metal bond breakage detected by fs X-ray scattering in the photolysis of Ru3(CO)12 in cyclohexane at 400 nm

Photochem. Photobiol. Sci., 2018, Accepted Manuscript
DOI: 10.1039/C8PP00420J, Paper

Qingyu Kong, Mads G. Laursen, Kristoffer Haldrup, Kasper Skov Kjær, Dmitry Khakhulin, Elisa Biasin, Tim Brandt van Driel, Michael Wulff, Victoria KABANOVA, Rodolphe Vuilleumier, Savo Bratos, Martin Meedom Nielsen, Kelly Gaffney, Tsu-chien Weng, Michel H.J. Koch
Using femtosecond resolution X-ray solution scattering at a free electron laser we were able to directly observe metal-metal bond cleavage upon photolysis at 400 nm of Ru3(CO)12, a prototype for...
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